668993-04-2

Upstream product

• 57099-04-4 3-O-benzyl-1,2-O-isopropylidene-α-D-allofuranose 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 668993-08-6 6-O-(3,5-di-O-benzyl-6-deoxy-1,2-O-isopropylidene-α-D-allofuranos-6-yl)-3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-allofuranose 
• 668993-06-4 Trifluoro-methanesulfonic acid (R)-2-benzyloxy-2-((3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 
• 668993-05-3 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-allofuranose 
• 217089-45-7 3,5-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-1,2-O-isopropylidene-α-D-allofuranose 
• 70448-45-2 3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-pentofuranose-4-nitrile 
• 881895-09-6 [(S)-2-Azido-2-((3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethoxy]-tert-butyl-diphenyl-silane 
• 881894-82-2 (S)-2-Azido-2-((3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanol 

Relevant academic research and scientific papers

Evidence on the structure of coyolosa. Synthesis of 6,6′-ether linked hexoses

The structure previously reported for coyolosa, a hypoglycemic substance isolated from natural sources, as a 6,6′-ether linked pseudo-disaccharide derived from allose, is incorrect since 6-O-(6-deoxy-D-allos-6-yl)-D-allose 10, synthesised by an unequivoca

New one-carbon degradative transformation of β-alkyl-β-azido alcohols

A new transformation of 2-azido-1-hydroxy-containing compounds to nitriles with one carbon less than the starting materials by oxidation was reported. The reaction can be performed under mild conditions.

Synthesis of 6,6'-ether linked disaccharides from D-allose, D-galactose, D-glucose and D-mannose; evidence on the structure of coyolosa.

6,6'-Linked ethers derived from D-allose, D-galactose, D-glucose, and D-mannose have been prepared in order to allow comparisons with the reported 6,6'-linked hexopyranose coyolosa, an hypoglycemic compound which has been isolated by extraction of the roo