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4-(2',4'-DINITROPHENYLAZO)-PHENOL, commonly known as Sudan I, is a synthetic red azo dye that is used in industrial applications and was once used as a food colorant. It is characterized by its bright red color and is insoluble in water but soluble in organic solvents. However, it has been identified as a carcinogen, causing cancer in laboratory animals, and is known to cause skin and eye irritation, inflammation, and allergic reactions in humans.

6690-51-3

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6690-51-3 Usage

Uses

Used in Industrial Applications:
Sudan I is used as a colorant in various industrial applications due to its bright red color and solubility in organic solvents. Its use in these applications is regulated to minimize potential health risks.
Used in Research and Analysis:
In some cases, Sudan I may be used in laboratory settings for research and analysis purposes, particularly in studies related to the detection and analysis of dyes and their effects.
However, it is important to note that due to the potential health risks associated with Sudan I, its use as a food additive has been banned in several countries, including the European Union. There is a continuous effort to limit the presence of Sudan I in the environment and to find safer alternative colorants for both industrial and food applications.

Check Digit Verification of cas no

The CAS Registry Mumber 6690-51-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,6,9 and 0 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 6690-51:
(6*6)+(5*6)+(4*9)+(3*0)+(2*5)+(1*1)=113
113 % 10 = 3
So 6690-51-3 is a valid CAS Registry Number.
InChI:InChI=1/C12H8N4O5/c17-10-4-1-8(2-5-10)13-14-11-6-3-9(15(18)19)7-12(11)16(20)21/h1-7,17H/b14-13-

6690-51-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(2,4-Dinitrophenylazo)phenol

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6690-51-3 SDS

6690-51-3Relevant academic research and scientific papers

Responsive ruthenium complex probe for phosphorescence and time-gated luminescence detection of bisulfite

Du, Zhongbo,Liu, Chaolong,Liu, Jianping,Song, Bo,Wang, Yong-Lei,Xi, Xiuyan,Yuan, Jingli,Zhang, Run,Zhang, Wenzhu

, p. 5531 - 5538 (2020/05/13)

Sensitive and selective quantification of specific analytes is of great significance in analytical and environmental sciences, as well as in the food industry. Herein, we report the design, synthesis, characterization, and application of a responsive ruth

Solvatochromism of new substituted 4-[(E)-(4-nitrophenyl)diazenyl]phenolate dyes

de Melo, Carlos E.A.,Nicoleti, Celso R.,Nandi, Leandro G.,Schneider, Felipe S.S.,da S. Oliboni, Robson,Caramori, Giovanni F.,Machado, Vanderlei G.

, (2020/01/30)

Studies on the reverse solvatochromism of dyes in pure solvents are of interest to gain a better understanding of the nature of this phenomenon. In this paper, a series of nine compounds, exhibiting phenol and 4-nitrophenyl groups linked with an azo conjugated bridge, was synthesized and characterized. These compounds were deprotonated to generate solvatochromic phenolate dyes. The azo bridge makes the phenol more acidic, in comparison with the related compounds exhibiting a CH[dbnd]CH or CH[dbnd]N bridge in their molecular structure, indicating the electron withdrawing character of the azo bridge. The solvatochromism of the dyes was investigated in 29 solvents and their intense colors in solution were attributed to π-π* electronic transitions, with an intramolecular charge transfer from the phenolate towards the 4-nitroaryl group. The probes exhibited a reversal in their solvatochromism, in a similar fashion to the behavior verified with related dyes presenting CH[dbnd]CH or CH[dbnd]N as the conjugated bridge; however, the azo dyes are much less sensitive to solvent polarity changes. Multiparametric analysis showed that the azo dyes are very sensitive to the acidity of the medium, but still to a lesser degree than the corresponding imine and stilbene dyes, due to the electronegativity of the azo group. The reverse solvatochromism of the dyes is dictated by the electron-donor phenolate and by the electron-acceptor 4-nitroaryl groups, independently of the conjugated bridge, of the additional nitro group and of the nature of substituents in the 2,6-positions of the phenolate groups. Thus, the solvatochromic reversal verified represents a committed step involving the interaction of the nitro and phenolate groups in the probe with the molecules of structurally different solvents.

A method of preparing azo dye through coupling

-

Paragraph 0039-0042, (2018/05/30)

The invention relates to an azo dye synthetic method, and particularly relates to a method of coupling a weak-alkaline arylamine diazonium salt and a phenol compound under alkaline conditions to prepare azo dye. Weak-alkaline arylamine diazonium salt filt

BASIC PROPERTIES OF 4-ARYLAZO-PHENOLS AND 4-ARYLAZO-ANISOLES

Nesterowicz, Marianna,Korewa, Ryszard

, p. 1085 - 1092 (2007/10/02)

The conditions in which 4-arylazo-phenols and 4-arylazo-anisoles have basic properties have been studied.We have also determined the equilibrium constants of the reactions between 4-arylazo-phenols or 4-arylazo-anisoles with perchloric acid in nitromethane, acetonitrile and acetic acid.Conclusions have been drawn from the influence of the nature of solvent and substituent at the benzene ring on equilibrium constant values.

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