66923-41-9

Upstream product

• 528-76-7 2,4-dinitrobenzenesulfenyl chloride 
• 20607-43-6 sodium isopropanethiolate 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 2218-96-4 2,4-dinitrothiophenol 
• 75-26-3 isopropyl bromide 

Downstream Products

• 70415-95-1 1,2,4-tris(isopropylthio)benzene 
• 70415-96-2 1,2,4-Tris-(propane-2-sulfonyl)-benzene 

Relevant academic research and scientific papers

Co-C bond cleavage in the reactions of alkyl, benzyl and heteroaromaticmethyl cobaloximes with arene sulfenyl chloride: Homolytic and heterolytic pathways

The reactions of arene sulfenyl chlorides, ArSCl, (Ar=Ph, C6Cl5, 2,4 (NO2)2C6H3) with organocobaloximes, RCo(dmgH)2Py, (R=alkyl, benzyl and heteroaromaticmethyl) were carried out under thermal and photochemical conditions. A variety of organic and organometallic products are formed depending upon the substrate cobaloxime. For 3-methoxybenzyl and heteroaromaticmethyl cobaloximes the results suggest that they represent a unique class of cobaloximes whereby both the aromatic ring as well as the Co-C bond are highly activated towards attack by the arene sulfenyl chloride. Both homolytic as well as heterolytic pathways are operative.