66934-76-7Relevant academic research and scientific papers
Manganese-Catalyzed Electrochemical Deconstructive Chlorination of Cycloalkanols via Alkoxy Radicals
Allen, Benjamin D. W.,Hareram, Mishra Deepak,Seastram, Alex C.,McBride, Tom,Wirth, Thomas,Browne, Duncan L.,Morrill, Louis C.
supporting information, p. 9241 - 9246 (2019/11/19)
A manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols has been developed. This electrochemical method provides access to alkoxy radicals from alcohols and exhibits a broad substrate scope, with various cyclopropanols and cyclobutanols converted into synthetically useful β- and γ-chlorinated ketones (40 examples). Furthermore, the combination of recirculating flow electrochemistry and continuous inline purification was employed to access products on a gram scale.
Tandem decarboxylative allylation and fragmentation of allyl benzocyclobutenyl carbonates: Access to ortho-functionalized aryls from aryl bromides
Rosa, David,Chtchemelinine, Andrei,Orellana, Arturo
experimental part, p. 1885 - 1891 (2012/08/14)
Allyl benzocyclobutyl carbonates yield ortho-allyl α-aryl ketones through a palladium-catalyzed decarboxylative allylation, fragmentation, and cross-coupling process. Georg Thieme Verlag Stuttgart · New York.
Preparation of benzocyclobutenols by low temperature reaction of ketone enolates with benzynes
Tripathy, Sasmita,Reddy, Ranga,Durst, Tony
, p. 997 - 1002 (2007/10/03)
The reaction of benzynes, generated from halobenzenes with lithium tetramethylpipiperide (LTMP) at -40 to -78°C, with ketone enolates affords benzocyclobutenols in fair to good yields.
