67007-27-6Relevant academic research and scientific papers
Anti-Markovnikov acetoxyphenylselenation of terminal alkenes
Vukievic,Radovi?
, p. 470 - 474 (2007/10/03)
Unexpected anti-Markovnikov acetoxyphenylselenation of terminal alkenes has been achieved by reaction of these substrates with diphenyl diselenide and lead tetraacetate in benzene under thermal conditions (80°C). The corresponding products, 1-acetoxy-2-phenylselenylhydrocarbons accompanied by their isomers, 2-acetoxy-1-phenylselenilhydrocarbons are obtained in moderate to good yields. Acetoxyphenylselenation with same reagents, but in acetic acid as the solvent, yields only expected Markovnikov products.
