6709-42-8

Basic information

• Product Name: N-(4-methoxyphenyl)-1,1-diphenylmethylamine
• Synonyms: N-(4-methoxyphenyl)-1,1-diphenylmethylamine
• CAS NO: 6709-42-8
• Molecular Weight: 289.377
• Mol File: 6709-42-8.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: N-(4-methoxyphenyl)-1,1-diphenylmethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methoxyphenyl)-1,1-diphenylmethylamine(6709-42-8)
• EPA Substance Registry System: N-(4-methoxyphenyl)-1,1-diphenylmethylamine(6709-42-8)

Safety Data

• Hazardous Substances Data: 6709-42-8(Hazardous Substances Data)

Upstream product

• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 3717-21-3 (E)-4-methoxybenzaldoxime 
• 39031-27-1 4-methoxy-benzaldehyde-(O-carbamoyl oxime ) 
• 143-66-8 sodium tetraphenyl borate 
• 91-01-0 1,1-Diphenylmethanol 
• 104-94-9 4-methoxy-aniline 
• 119-61-9 benzophenone 
• 100-46-9 benzylamine 
• 591-51-5 phenyllithium 
• 623-12-1 4-chloromethoxybenzene 
• 91-00-9 Benzhydrylamine 
• 459-60-9 1-fluoro-4-methoxybenzene 
• 908093-98-1 diazodiphenylmethane 
• 4545-20-4 benzophenone tosylhydrazone 

Downstream Products

• 114792-63-1 N-benzhydryl-N-(4-methoxy-phenyl)-N'-phenyl-urea 
• 102459-38-1 acetic acid-(N-benzhydryl-p-anisidide) 

Relevant articles and documents

Silver-Catalyzed N-H Functionalization of Aryl/Aryl Diazoalkanes with Anilines

Herein, we report on the N-H functionalization reaction of primary and secondary anilines with diaryldiazoalkanes using simple AgPF6 as catalyst. We demonstrated broad applicability in the reaction of diaryldiazoalkanes with different anilines (31 examples, up to 97% yield). Furthermore, we propose a possible reaction mechanism for the N-H functionalization.

Borane-Catalyzed Chemoselectivity-Controllable N-Alkylation and ortho C-Alkylation of Unprotected Arylamines Using Benzylic Alcohols

An unprecedented protocol for the efficient and highly chemoselective alkylation of unprotected arylamines using alcohols catalyzed by B(C6F5)3 has been developed. The reaction gives N-alkylated products and ortho C-alkylated products in different solvents in good chemoselectivities and yields. Control experiments and DFT calculations indicated that the borane underwent alcohol/arylamine exchange to ensure catalytic activity, and a possible mechanism involving a carbocation is proposed.

Hydrogen-Borrowing Amination of Secondary Alcohols Promoted by a (Cyclopentadienone)iron Complex

Thanks to a highly active catalyst, the scope of the (cyclopentadienone)iron complex-promoted 'hydrogen-borrowing' (HB) amination has been expanded to secondary alcohols, which had previously been reported to react only in the presence of large amounts of co-catalysts. A range of cyclic and acyclic secondary alcohols were reacted with aromatic and aliphatic amines giving fair to excellent yields of the substitution products. The catalyst was also able to promote the cyclization of diols bearing a secondary alcohol group with primary amines to generate saturated N-heterocycles.