671773-85-6

Basic information

• Product Name: [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)]
• CAS NO: 671773-85-6
• Molecular Weight: 904.804
• Mol File: 671773-85-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)](671773-85-6)
• EPA Substance Registry System: [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)](671773-85-6)

Safety Data

• Hazardous Substances Data: 671773-85-6(Hazardous Substances Data)

Upstream product

• 225092-99-9 [Ru2(CO)4(μ-H)(μ-P(t)Bu2)(μ-dppm)] 
• 10102-43-9 nitrogen(II) oxide 

Relevant articles and documents

Reductive Dimerization of Nitric Oxide to trans-Hyponitrite in the Coordination Sphere of a Dinuclear Ruthenium Complex

During the reaction of the coordinatively unsaturated compound [Ru 2(CO)4(μ-H)(μ-PBu2 t)-(μ-dppm)] (1; dppm = Ph2PCH2PPh 2) with nitric oxide, the latter dimerizes and yields the unusual toms-hyponitrite complex [Ru2(CO)4(μ-H)(μ-PBu 2t)(μ-dppm)(μ-η2-ONNO)] (2). The molecular structure of 2 has been determined by X-ray diffraction and is discussed together with the results of DFT calculations. The compound stands out by having only one of the two hyponitrite NO units bonded to Ru. The second one is not connected to Ru but in the solid state exhibits a weak intramolecular bond to the carbon atom of a neighboring carbonyl group.