67191-36-0Relevant articles and documents
SULFAMATE DERIVATIVE COMPOUNDS FOR USE IN TREATING OR ALLEVIATING PAIN
-
, (2015/06/25)
The present invention relates to sulfamate derivative compounds and a composition for treating and/or alleviating pain containing the sulfamate derivative compounds or a pharmaceutically acceptable salt thereof as an active ingredient. More specifically,
Chemo-, Regio-, and stereoselective trifluoromethylation of styrenes via visible light-driven single-electron transfer (SET) and triplet-triplet energy transfer (TTET) processes
Lin, Qing-Yu,Xu, Xiu-Hua,Qing, Feng-Ling
, p. 10434 - 10446 (2015/02/19)
A process for tunable and chemo-, regio-, and stereoselective photocatalytic trifluoromethylation of styrenes was developed. Thermodynamically stable E-trifluoromethylated alkenes were prepared using Tognis reagent in the presence of Ru(bpy)3Cl2·6H2O under visible light irradiation, whereas less thermodynamically stable Z-trifluoromethylated alkenes were obtained by employing Umemotos reagent and photocatalyst Ir(ppy)3.
Efficient heterogeneous vinylation of aryl halides using potassium vinyltrifluoroborate
Joucla, Lionel,Cusati, Giuseppe,Pinel, Catherine,Djakovitch, Laurent
, p. 4738 - 4741 (2008/12/21)
An efficient heterogeneously palladium catalysed procedure for the vinylation of aryl iodides and bromides is reported. Using common reaction conditions (Pd/C 2 mol %, AcONa·3H2O, NMP or NMP/H2O), good to complete conversions (40-100%) with high selectivities (79-100%) towards the expected vinylaromatic were achieved.