67223-99-8

Basic information

• Product Name: Ethanone, 1-(2-methyl-1-cyclobuten-1-yl)- (9CI)
• Synonyms: Ethanone, 1-(2-methyl-1-cyclobuten-1-yl)- (9CI)
• CAS NO: 67223-99-8
• Molecular Formula: C₇H₁₀O
• Molecular Weight: 110.1537
• Product Categories: ACETYLGROUP
• Mol File: 67223-99-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(2-methyl-1-cyclobuten-1-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-methyl-1-cyclobuten-1-yl)- (9CI)(67223-99-8)
• EPA Substance Registry System: Ethanone, 1-(2-methyl-1-cyclobuten-1-yl)- (9CI)(67223-99-8)

Safety Data

• Hazardous Substances Data: 67223-99-8(Hazardous Substances Data)

Upstream product

• 86994-12-9 2-methyl-1-(trimethylsilyl)cyclobutene 
• 75-36-5 acetyl chloride 
• 83467-42-9 C₁₄H₁₈N₂O₃S 

Downstream Products

• 131510-76-4 1-(3-Methyl-4-phenyl-cyclohex-3-enyl)-ethanone 
• 131510-75-3 1-(4-Methyl-3-phenyl-cyclohex-3-enyl)-ethanone 
• 6090-09-1 (+-)-4-acetyl-1-methylcyclohexene 
• 128352-65-8 1-(3,4-dimethylcyclohex-3-enyl)ethanone 
• 55695-36-8 1-(3,3,4-trimethyl-cyclohex-3-enyl)-ethanone 
• 131510-64-0 1-acetyl-2-methyl-2-vinylcyclobutane 
• 344747-11-1 2-acetyl-1-allyl-1-methylcyclobutane 
• 122598-68-9 1-(6-Methyl-bicyclo[4.2.0]oct-3-en-1-yl)-ethanone 
• 131510-77-5 1-[2-Methyl-2-(1-phenyl-vinyl)-cyclobutyl]-ethanone 
• 131510-65-1 1-Acetyl-2-isopropenyl-2-methylcyclobutane 
• 173829-77-1 1-acetyl-2-methyl-2-vinylcyclobutane 
• 173829-77-1 1-acetyl-2-methyl-2-vinylcyclobutane 

Relevant articles and documents

RAMFORD-STEVENS REACTION IN THE SERIES OF 1-ACYL-1-R-CYCLOPROPANES

Investigation of the relationships governing the carbene decomposition of the monotosylhydrazones of 1-R-1-acylcyclopropanes showed that ?-accepting substituents at the gem position to the carbonyl group increase the stability of the three-membered ring under the conditions of the Bamford-Stevens reaction.This leads to partial suppression of the cyclopropylmethyl-cyclobutene isomerization process and, as a result, to the formation of 1,1-gem-alkenylcyclopropanes and bicyclobutanes.