67249-78-9Relevant articles and documents
Methoxy- and Aminoisocyanate
Teles, Joaquim Henrique,Maier, Guenther
, p. 745 - 748 (2007/10/02)
Methoxyisocyanate (1) can be prepared by photolysis of methyl azidoformate (3) or pyrolysis of N-methoxycarbonyl-O-methylhydroxylamine (4).Aminoisocyanate (2) is similarly formed on photolysis of carbamoyl azide (12) and pyrolysis of either methyl carbazate (13) or 3,4-diaminofurazan (14).The infrared spectra of 1 and 2 in an argon matrix at 10 K have been measured, and some of their properties are discussed. - Keywords: Flash pyrolysis/ Matrix IR spectroscopy/ Photolysis