67259-61-4

Basic information

• Product Name: 4-FLUOROPHENYL-ALPHA-OXOKETENE-GEM-DITHIOL
• Synonyms: 4-FLUOROPHENYL-ALPHA-OXOKETENE-GEM-DITHIOL;1-(4-Fluorophenyl)-3,3-dimercaptoprop-2-en-1-one;1-(4-FLUOROBENZOYL)ETHYLENE-2,2-DITHIOL;1-(4-Fluorobenzoyl)ethylene-2,2-dithiol 97%;1-(4-Fluorobenzoyl)ethylene-2,2-dithiol97%
• CAS NO: 67259-61-4
• Molecular Formula: C₉H₇FOS₂
• Molecular Weight: 214.28
• Mol File: 67259-61-4.mol
• Article Data: 1

Chemical Properties

• Melting Point: 67°C
• Boiling Point: 310.9°C at 760 mmHg
• Flash Point: 141.8°C
• Appearance: /
• Density: 1.313g/cm³
• Vapor Pressure: 0.000585mmHg at 25°C
• Refractive Index: 1.61
• Sensitive: Stench
• CAS DataBase Reference: 4-FLUOROPHENYL-ALPHA-OXOKETENE-GEM-DITHIOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-FLUOROPHENYL-ALPHA-OXOKETENE-GEM-DITHIOL(67259-61-4)
• EPA Substance Registry System: 4-FLUOROPHENYL-ALPHA-OXOKETENE-GEM-DITHIOL(67259-61-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 67259-61-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H7FOS2/c10-7-3-1-6(2-4-7)8(11)5-9(12)13/h1-5,12-13H

Upstream product

• 75-15-0 carbon disulfide 
• 403-42-9 1-(4-fluorophenyl)ethanone 

Downstream Products

• 623149-66-6 [Fe2(CO)6(μ-S2C=CHC(O)C6H4F)] 
• 251940-06-4 1-(4-fluorophenyl)-2-(imidazolidin-2-ylidene)ethan-1-one 

Relevant articles and documents

Synthesis of densely substituted 1,3-butadienes through acid-catalyzed alkenylations of α-oxoketene dithioacetals with aldehydes

Aldehydes were proved to be viable reagents for implementing alkenylation of α-oxoketene dithioacetals. AlCl3 was found to be the best catalyst. The established reaction opened an avenue to access densely substituted 1,3-butadiene derivatives. The obtained product bears multiple reactive sites that can be converted into various valuable molecules. (Chemical Equation Presented).