67274-99-1Relevant academic research and scientific papers
Substitution and Elimination Reactions via One Electron Transfer Process. A New Olefin Synthesis from β-Nitro Sulfones
Ono, Noboru,Tamura, Rui,Nakatsuka, Tamon,Hayami, Jun-ichi,Kaji, Aritsune
, p. 3295 - 3300 (2007/10/02)
gem-Bromonitro compounds or gem-dinitro compounds couple with carbanions derived from α-cyano sulfones or α-carbonyl sulfones to give β-nitro sulfones.The nitro and sulfonyl groups are eliminated from the coupling products on treatment with reductive one electron transfer reagents to give α,β-unsaturated carbonyl compounds or nitriles.
