67280-33-5

Basic information

• Product Name: 7,12-dihydro-5H-6,12-methanodibenzo[c,f]azocine
• CAS NO: 67280-33-5
• Molecular Formula: C₁₆H₁₅N
• Molecular Weight: 221.297
• Mol File: 67280-33-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 342.8°C at 760 mmHg
• Flash Point: 145.9°C
• Density: 1.19g/cm³
• Vapor Pressure: 7.36E-05mmHg at 25°C
• Refractive Index: 1.679
• CAS DataBase Reference: 7,12-dihydro-5H-6,12-methanodibenzo[c,f]azocine(CAS DataBase Reference)
• NIST Chemistry Reference: 7,12-dihydro-5H-6,12-methanodibenzo[c,f]azocine(67280-33-5)
• EPA Substance Registry System: 7,12-dihydro-5H-6,12-methanodibenzo[c,f]azocine(67280-33-5)

Safety Data

• Hazardous Substances Data: 67280-33-5(Hazardous Substances Data)

Upstream product

• 106889-85-4 N-benzyl-4-ethoxy-1,2,3,4-tetrahydroisoquinoline 
• 67280-28-8 (N,N-dibenzyl)aminoacetaldehyde diethyl acetal 

Downstream Products

• 67280-36-8 6-methyl-12-methylene-5,6,7,12-tetrahydro-dibenzo[c,f]azocine 

Relevant articles and documents

ACID-CATALYZED DOUBLE-CYCLIZATION REACTIONS OF N,N-DIBENZYLAMINO-ACETALDEHYDE DIALKYL ACETALS AND RELATED COMPOUNDS: GENERAL SYNTHESIS OF 7,12-DIHYDRO-5H-6,12-METHANODIBENZAZOCINES AND RELATED COMPOUNDS

A number of N,N-dibenzylaminoacetaldehyde dialkyl acetals (1) double-cyclized in 70percent perchloric acid or triflic acid (trifluoromethanesulfonic acid) to give good yields of 7,12-dihydro-5H-6,12-methanodibenzazocines (2) even when a powerful elec