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Allenes and Acetylenes. XXIV. Synthesis of α-Allenic Amines by Organocuprate Reactions of Acetylenic Aminoethers
Sahlberg, Christer,Claesson, Alf
, p. 179 - 186 (2007/10/02)
Tertiary α-allenic amines 1a - d are formed in good yields in reactions of acetylenic aminoethers with an organocuprate reagent, derived from butylmagnesium bromide and 5-20percent of CuI, in tetrahydrofuran (THF) or THF-diethyl ether 3:1.The overall redu
