67282-70-6Relevant academic research and scientific papers
A NEW COMBINED OXIDIZING REAGENT SYSTEM, Fe(CH3CN)6(3+)-IO4(1-): OXIDATION OF PARAFFIN HYDROCARBONS
Kotani, Eiichi,Kobayashi, Shigeki,Ishii, Yoko,Tobinaga, Seisho
, p. 4680 - 4684 (2007/10/02)
Combined oxidizing reagent systems of Fe(AN)6ClO4)3 ( AN = acetonitrile ) with halogen oxyacids were investigated.In particular, reactions of paraffin hydrocarbons with a combined reagent system of Fe(AN)6(3+) were explored because of the high reactivity of this system in the oxidation of adamantane ( Table 1 ).Oxidation of bornane, norbornane, cyclohexane, and n-hexane gave the corresponding acetamides and acetates ( Tabla II ).These results shows that the title reagent system can efficiently oxidize organic substrates which have onset potentials of anodic current of ca. 2.7 V vs. saturated calomel electrode.Keywords - oxidation; paraffin hydrocarbon; combined reagent system; hexakisacetonitrile iron(III) perchlorate; halogen oxyacid; sodium periodate
