67292-34-6

Basic information

• Product Name: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
• Synonyms: Ni(dppf)Cl2;[1,1'-Bis(diphenylphosphino)ferrocene]nickel(II) chloride, 99%;[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(Ⅱ);[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II),98%;Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II),98% (DPPF)NiCl2;[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II);[1,1'-Bis(diphenylphosphiNA)ferrocene]dichloronickel(II);[1,1'-Bis(diphenylphosphino)fe
• CAS NO: 67292-34-6
• Molecular Formula: C₃₄H₂₈Cl₂FeNiP₂
• Molecular Weight: 683.98
• Product Categories: Ni;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Metallocenes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Metal Compounds;pharmacetical
• Mol File: 67292-34-6.mol
• Article Data: 13

Chemical Properties

• Melting Point: 285 °C (dec.)(lit.)
• Appearance: green micro/crystal
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: Insoluble in water.
• CAS DataBase Reference: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)(67292-34-6)
• EPA Substance Registry System: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)(67292-34-6)

Safety Data

• Hazard Codes: T
• Statements: 45-42/43
• Safety Statements: 53-22-36/37/39-45
• RIDADR: 2811
• WGK Germany: 3
• Hazardous Substances Data: 67292-34-6(Hazardous Substances Data)

Usage

Chemical Properties

Yellow powder

Uses

Different sources of media describe the Uses of 67292-34-6 differently. You can refer to the following data:
1. diphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals.
2. (1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines.
3. suzuki reaction

Upstream product

• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 
• 83864-14-6 nickel dichloride 
• 201230-82-2 carbon monoxide 
• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 

Downstream Products

• 162476-91-7 [(1,1′-bis(diphenylphosphino)ferrocene)Ni⁽⁰⁾(1,5-cyclooctadiene)] 
• 160260-01-5 dicarbonyl[bis(diphenylphosphino)ferrocene]nickel⁽⁰⁾ 

Relevant articles and documents

Synthetic, electrochemical, and structural studies on heterobimetallic crown thioether complexes with Group 10 metals: The crystal structures of [Pt(9S3)(dppf)](PF6)2·CH3NO2 and [Pd(9S3)(dppf)](PF6)2·CH3NO2

The syntheses, electrochemistry, and crystal structures for two new Pt(II) and Pd(II) heteroleptic bimetallic complexes with the crown trithioether 1,4,7-trithiacyclononane (9S3) and the diphosphine ligand, 1,1′-bis(diphenylphosphino)ferrocene (dppf) are reported. Both complexes have the general formula [M(9S3)(dppf)](PF6)2 (M=Pt or Pd) and exhibit the anticipated structure forming a distorted cis square planar array of two sulfur atoms from the 9S3 and two phosphorus atoms. These are, to our knowledge, the first reported examples of dppf transition metal complexes involving a thioether as the ancillary ligand. The dppf ligand functions as a bidentate chelator to a single metal center, and the third 9S3 sulfur atom does interact with the metal ion from a greater distance (Pt-S=2.8167(8) ?; Pd-S=2.7916(5) ?) to yield an elongated square pyramidal geometry. The two structures are isomorphous with very similar bond distances and angles. The values for the 31P-NMR chemical shifts (Pt=15.09 ppm, Pd=-0.47 ppm), the 195Pt-NMR chemical shift for the Pt(II) complex (-4353 ppm) and 1J(195Pt-31P) coupling constants (3511 Hz) are all consistent with a cis-MS2P2 square planar coordination sphere. The 9S3 ligand is fluxional in solution for both complexes. The electrochemistry of both complexes is dominated by a reversible Fe(II)/Fe(III) couple from the ferrocene moiety (E1/2=+721 mV for Pt(II), +732 mV for Pd(II), both versus Fc/Fc+).

METHOD FOR PREPARATION OF FLUORO ALKYLATED COMPOUNDS BY HOMOGENEOUS NI CATALYSIS

The invention discloses a method for the preparation of fluoro alkylated compounds by homogeneous Ni catalyzed fluoro alkylation with fluoro alkyl halides in the presence of a base.

Selective nickel-catalyzed fluoroalkylations of olefins

Mild and selective nickel-catalyzed trifluoromethylation and perfluoroalkylation reactions of alkenes were developed to provide fluorinated olefins, including natural products, pharmaceuticals, and variety of synthetic building blocks in good to excellent