6730-18-3

Usage

Molecular structure

1-[2,3,4,5,6-pentakis(acetyloxy)cyclohexyl]triaza-1,2-dien-2-ium is a complex chemical compound with a cyclohexyl ring and a triaza-1,2-dien-2-ium moiety.

Functional groups

The compound has five acetyloxy groups attached to the cyclohexyl ring, which are ester functional groups.

Derivative

It is a cyclohexyltriaza-1,2-dien-2-ium derivative, which is a type of chemical compound derived from the triaza-1,2-dien-2-ium moiety.

Applications

The compound is used in organic synthesis and medicinal chemistry due to its unique structure and functional groups.

Versatility

Its structure and functional groups make it a versatile building block for the synthesis of various organic compounds.

Potential properties

The compound is of interest for its potential biological and pharmacological properties, which could be explored in future research.

Fields of interest

1-[2,3,4,5,6-pentakis(acetyloxy)cyclohexyl]triaza-1,2-dien-2-ium has potential applications in various fields of science and industry, including pharmaceuticals, materials science, and chemical engineering.

Upstream product

• 108-24-7 acetic anhydride 
• 13462-79-8 1⁽³⁾,4⁽⁶⁾,5,6⁽⁴⁾-tetra-O-acetyl-sn-myo-inositol 
• 31077-18-6 1,2,3,4,5,-penta-O-acetyl-6-bromo-6-deoxy-scyllo-inositol 
• 639079-43-9 (-)-3,4,5-tri-O-acetyl-6-azido-myo-inositol 
• 169529-92-4 (+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 140696-30-6 (1R,2S,3R,6R)-2-bromo-7-oxabicyclo[4.1.0]hept-4-en-3-ol 
• 639079-40-6 (1R,2S,3R,6S)-6-azido-2-bromocyclohex-4-ene-1,3-diol 
• 639079-41-7 (1S,2R,3R,4S)-1-azidoconduritol B 
• 639799-14-7 (1S,2R,3R,4S)-2,3,4-tri-O-acetyl-1-azidoconduritol B 
• 52432-16-3 (+)-3-deoxy-3-azido-myo-inositol 
• 639079-44-0 (+)-4,5,6-tri-O-acetyl-3-azido-myo-inositol 
• 639079-54-2 (+)-1,5,6-tri-O-acetyl-4-azido-myo-inositol 
• 169529-93-5 (-)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 251538-17-7 (1S,2R,3S,6R)-6-azido-2-bromocyclohex-4-ene-1,3-diol 

Relevant academic research and scientific papers

Chemoenzymatic synthesis of hygromycin aminocyclitol moiety and its C2 epimer

This manuscript describes the enantioselective synthesis of the aminocyclitol moiety of the antibiotic hygromycin A in eight steps and 39 % overall yield from a non-chiral starting material. The sequence made use of an initial enzymatic step to transfer chirality to an aromatic ring and was followed by selective organic chemistry transformations (oxidation, pro-tection, azidation, hydrolysis) of the six-membered ring in order to achieve the target. The approach is also amenable to the synthesis of other related unnatural analogues as exemplified by the synthesis of the C2 epimer of the natural aminocyclitol. All the intermediates were fully characterized, and the absolute stereochemistry assigned by spectrometric methods.

Stereoselective synthesis of several azido/amino- and diazido/diamino-myo-inositols and their phosphates from p-benzoquinone

A practical route is described for the preparation of azido-myo-inositols, amino-myo-inositols and azido-conduritol B derivatives. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol B derivative. Selective introduction of nitrogen-containing functional groups in four of the six possible positions in the cyclitol moiety is followed by further functionalization to yield the target compounds.

Convenient access to both enantiomers of new azido- and aminoinositols via a chemoenzymatic route

1,2-diacetylconduritol E, (±)-1, through complementary use of Mucor miehei (Lipozyme IM) and Candida cylindracea lipases, affords (1S)-1,2- diacetylconduritol E, (+)-1, (1R)-1,2-diacetylconduritol E, (-)-1, (1S)- 1,2,4-triacetylconduritol E, (+)-2, (1R)-1

Total Synthesis of Methoxyhygromycin and Its 5-Epimer

Methoxyhygromycin, an antibiotic having a unique structure among the aminocyclitol antibiotics, and its 5-epimer are first synthesized.This synthesis fully confirmed the proposed structure of the antibiotic and revealed that neo-configuration of cyclitol

Cyclitol Reactions, XII. - Enantioselective Synthesis of the Central Pseudodisaccharide Unit of α-Glycosidase Inhibitors of the Oligostatine Type

A pseudodisaccharide unit of the α-glycosidase inhibitors of the oligostatine type has been synthesized.At first a synthesis of the enantiomeric pure derivative of the branched amino inositol 26 has been developed.A linkage of 26 with the reactive epoxide