67340-90-3

Upstream product

• 928-94-9 (Z)-2-hexen-1-ol 
• 71655-17-9 (E)-3-hexen-1,6-diol 
• 6728-26-3 (E)-2-Hexenal 
• 88730-62-5 Triphenyl-[(Z)-6-(tetrahydro-pyran-2-yloxy)-hex-3-enyl]-phosphonium; iodide 
• 130236-43-0 (E)-6-(2-tetrahydropyranyloxy)-hex-3-enyltriphenyl phosphonium iodide 
• 128120-09-2 3,6,8-dodecatrien-1-ol THP ether 
• 130236-41-8 (3E)-1-iodo-6-(2-tetrahydropyranyloxy)-hex-3-ene 
• 130236-40-7 E-6-(tetrahydro-2Hpyran-2-yloxy)hex-3-enyl 4-methylbenzenesulfonate 
• 29311-53-3 (E)-3-hexene-1,6-dioic acid 
• 88730-60-3 (E)-6-(tetrahydro-2H-pyran-2-yloxy)hex-3-en-1-ol 
• 16635-54-4 (Z)-2-hexenal 
• 88730-61-4 1-Iodo-6-<(2-tetrahydropyranyl)oxy>-(Z)-hex-3-ene 

Relevant academic research and scientific papers

Syntheses and NMR analyses of the eight geometric isomers of 3,6,8-dodecatrien-1-ol, subterranean termite trail pheromone

Eight geometric isomers of 3,6,8-dodecatrien-1-ol 1, the trail-following pheromone of subterranean termites (Reticulitermes sp. Banks), were synthesized via a Wittig olefination reaction. The convergent syntheses of 1 consisted of a combination of two fragments, each containing an olefin with a fixed configuration, by formation of a third double bond to give a mixture of two geometric isomers. The mixtures of 1 were resolved by recycle high-performance liquid chromatography methods. 1H and 13C NMR peak assignments of the individual isomers were accomplished by homonuclear COSY, and one-bond CH correlation spectroscopy.