67350-85-0

Basic information

• Product Name: 2,4-Nonadiene, 2-methyl-, (E)-
• CAS NO: 67350-85-0
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Mol File: 67350-85-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-Nonadiene, 2-methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Nonadiene, 2-methyl-, (E)-(67350-85-0)
• EPA Substance Registry System: 2,4-Nonadiene, 2-methyl-, (E)-(67350-85-0)

Safety Data

• Hazardous Substances Data: 67350-85-0(Hazardous Substances Data)

Upstream product

• 5722-11-2 rac-2,2-dimethylcyclopropanecarbonitrile 
• 592-41-6 1-hexene 
• 3017-69-4 2-methyl-1-propenylbromide 
• 90047-75-9 1-Iodo-8-methyl-6,7-nonadiene 

Relevant articles and documents

Cyclizations of ω-Allenyl Radicals

Allenyl halides of structure (CH3)2C=C=CH(CH2)nX with n=3-6 have been prepared and reacted with n-Bu3SnH to generate the corresponding radicals for examination of the cyclization reactions of these reactive intermediates.The observed hydrocarbon products indicate that cyclization occurs for the n=3,4, and 5 radicals but not for the n=6 species.The n=3 radical isomerizes very efficiently by intramolecular addition to the sp carbon of the allene group.The n=5 intermediate reacts relatively slowly by attack at the near sp2 carbon.Both cyclization modes are observed for the n=4 species.The details of these radical cyclizations are discussed.