67399-71-7Relevant academic research and scientific papers
COOLIGOMERIZATION OF PROPADIENE WITH PROPYNE CATALYSED BY NICKEL(0) COMPLEXES
Cermak, Jan,Blechta, Vratislav,Chvalovsky, Vaclav
, p. 1274 - 1286 (2007/10/02)
Cooligomerization of propadiene with propyne catalysed by bis(1,5-cyclooctadiene)nickel and tetrakis(triphenylphosphine)nickel gives a variety of products, including besides the cooligomers also the homooligomers of both monomers.The type of catalyst affects partially the product distribution due to changes in the degree of oligomerization.Cooligomerization of propadiene with 3-deuteriopropyne provided information about relative proportion of propadiene and propyne units in the oligomers.
SOME CATALYTIC PROPERTIES OF Rh(diphos)(η-BPh4)
Albano, P.,Aresta, M.
, p. 243 - 246 (2007/10/02)
The covalent complex Rh(diphos)(η-BPh4) (I) reacts with CO in polar solvents to afford the cationic dicarbonyl cis-(BPh4).I is an effective catalyst for methylacetylene oligomerization and allene polymerization.In the presence of CO2 and methylacetylene, I affords 4,6-dimethyl-2-pyrone.
