1034474-09-3

Basic information

• Product Name: (μ-2-naphthyl)(AuPPh3)2ClO4
• CAS NO: 1034474-09-3
• Molecular Weight: 1145.13
• Mol File: 1034474-09-3.mol

Chemical Properties

• CAS DataBase Reference: (μ-2-naphthyl)(AuPPh3)2ClO4(CAS DataBase Reference)
• NIST Chemistry Reference: (μ-2-naphthyl)(AuPPh3)2ClO4(1034474-09-3)
• EPA Substance Registry System: (μ-2-naphthyl)(AuPPh3)2ClO4(1034474-09-3)

Safety Data

• Hazardous Substances Data: 1034474-09-3(Hazardous Substances Data)

Upstream product

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 580-13-2 2-bromonaphthalene 
• 7601-90-3 perchloric acid 
• 67430-86-8 (2-naphthyl)(triphenylphosphanyl)gold 

Relevant articles and documents

Photoluminescent properties and molecular structures of [NaphAu(PPh 3)] and [μ-Naph {Au(PPh3)}2] ClO4 (Naph = 2-naphthyl)

The complexes [NaphAu(PPh3)], 1 and [μ-Naph{Au(PPh 3)}2]ClO4, 2 having the Au-C (aromatic) bond have been synthesized and characterized. The unique structure of 2 with two gold atoms bridged by a naphthyl group has been determined by X-ray crystallography. The intramolecular Au-Au separation in 2 is 2.7731(4) A. Upon excitation at 266 nm, both complexes display intraligand phosphorescence at room temperature in solution and in solid state. This journal is The Royal Society of Chemistry.