674347-67-2

Upstream product

• 949587-17-1 2-(4-hydroxybutyl)-2-methyl-1,3-cyclohexanedione 
• 31929-07-4 2-allyl-2-methyl-1,3-cyclohexanedione 
• 107-02-8 acrolein 
• 674347-41-2 (E)-4-(1-methyl-2,6-dioxocyclohexyl)but-2-enal 
• 1193-55-1 2-methylcyclohexane-1,3-dione 

Downstream Products

• 949587-26-2 (1S,6S,9S)-9-(1-hydroxy-6-methyl-5-oxobicyclo[4.3.0]nonane)carbaldehyde 
• 674347-42-3 (1R,6R,9R)-9-(1-hydroxy-6-methyl-5-oxobicyclo[4.3.0]nonane)carbaldehyde 

Relevant academic research and scientific papers

Convenient preparation of synthetically useful chiral quaternary carbon-containing bicyclic compounds with organocatalysts

Chiral quaternary carbon-containing bicyclic compounds possessing carbonyl functionalities were efficiently synthesized through asymmetric intramolecular aldol reactions with organocatalysts. Bicyclo [3.3.0] and [3.4.0] systems were constructed with a dia

Organocatalyst-mediated enantioselective intramolecular aldol reaction featuring the rare combination of aldehyde as nucleophile and ketone as electrophile

(Chemical Equation Presented) The trifluoroacetic acid salt of 2-(pyrrolidinylmethyl)pyrrolidine was found to be an effective organocatalyst of an asymmetric intramolecular aldol reaction, affording bicyclo[4.3.0]nonane derivatives with a high enantiosele

Catalytic addition of metallo-aldehyde enolates to ketones: A new C-C bond-forming hydrogenation

The first catalytic cross-aldolization of metallo-aldehyde enolates with ketone acceptors is enabled via hydrogenation of keto-enals with cationic rhodium catalysts. These results, in conjunction with prior studies involving the catalytic hydrogen-mediate