67447-50-1Relevant academic research and scientific papers
Additive-free radical cascade reaction of oxime esters: Synthesis of pyrroline-functionalized phenanthridines
Shao, Liming,Xue, Yijie,Xue, Dengqi,He, Qian,Ge, Qianwei,Li, Wei
, p. 12284 - 12293 (2020/11/10)
A variety of dihydropyrrole-functionalized phenanthridines were efficiently synthesized by the metal-free, radical cascade cyclization reaction of 2-isocyanobiphenyls with γ,δ- unsaturated oxime esters. The C-N/C-C/C-C bonds were formed via the oil bath method in a one-pot procedure with broad substrate applicability. The radical process was supported by kinetic isotope effect studies and radical inhibition studies.
K2S2O8-mediated radical cyclisation of 2-alkynylthioanisoles or -selenoanisoles: a green and regioselective route to 3-nitrobenzothiophenes and benzoselenophenes
Gong, Ya-Ling,Lu, Shi-Chao,Wu, Botao,Xu, Shu,Zhang, Shi-Peng
, p. 19083 - 19087 (2020/06/08)
An acid, transition-metal, and chromatography-free radical nitration/cyclisation of 2-alkynylthioanisoles or -selenoanisoles has been developed. This is the first example of the use of highly unstable 2-nitrovinyl radicals for C-S bond formation. This facile route efficiently produces 3-nitrobenzothiophenes and benzoselenophenes, which are difficult to accessviaclassical methods. Density functional theory (DFT) calculations were carried out to probe the reaction mechanism. The resulting products were tested for theirin vitroanti-tuberculosis activity, and compounds2dand2lshowed significant activities against sensitive and drug-resistant strains.
HETERO-CYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
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Paragraph 0192-0193; 0202-0203, (2016/10/08)
In the present invention, provided are: a heterocyclic compound which can significantly extend lifespan and improve efficiency, electrochemical stability, and thermal stability of the organic light-emitting device; and an organic light-emitting device containing the heterocyclic compound in an organic compound layer. The heterocyclic compound is represented by chemical formula 1.COPYRIGHT KIPO 2016
ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL HAVING SILICON-CONTAINING FOUR MEMBERED RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
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Paragraph 0117, (2014/08/19)
Provided are a material for an organic electroluminescent element formed of a silicon-containing four-membered ring compound, and an organic electroluminescent element using the material. The material for an organic electroluminescent element is formed of
Benzo(B)thiophenes
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, (2008/06/13)
The present invention relates to new derivatives of 2-phenyl -benzo(b)thiophene mono- or disubstituted on the nitrogen atom of formula STR1 in which X1 to X9 which are identical or different are hydrogen, alkyl having up to 3 carbon
