67447-91-0Relevant academic research and scientific papers
Reactions of Ketenimines with Arene-sulfanyl and -selanyl Chlorides: a General Route to Secondary Amide Derivatives and a New Synthesis of C-Sulfanyl- and C-Selanyl-ketenimines
McCarthy, Daniel G.,McCutcheon, Patrick O.,Sheehan, Dermot P.
, p. 2899 - 2902 (2007/10/02)
Ketenimines 1, react with arene-sulfanyl and -selanyl chlorides to give the imidoyl chlorides 3 that either yield the substituted amides 4 upon solvolysis in aqueous acetone, or the C-sulfanyl- and C-selanyl-keteneimines 5 by dehydrochlorination with trie
Synthesis and Reactions of C-Sulphenylketenimines
Motoyoshiya, Jiro,Yamamoto, Iwao,Gotoh, Haruo
, p. 2727 - 2730 (2007/10/02)
The Horner-Wittig reaction of (1a,b) with phenyl isocyanate or dehydration of amides (4c-g) gave the C-sulphenylketenimines (3a-g) in moderate yields.Thermolysis of (3b) gave 2-ethoxy-3-phenylthioquinolin-4-ol (7) via intramolecular cyclization, and the r
