73778-49-1Relevant articles and documents
A simple protocol for the synthesis of α-substituted phosphonates
Wang, Xing,Cai, Yuan,Chen, Jian,Verpoort, Francis
, p. 1268 - 1273 (2016/08/31)
An efficient, easy-to-handle, and mild substitution reaction approach has been developed for the synthesis of phosphonate derivatives, which are very important in the field of industrial, agricultural, and medicinal chemistry. A large number of nucleophiles, including arylamines, alkylamines, heteroarylamines, primary amines and secondary amines, sulfides, and carbides were attempted to react with α-tosyloxyphosphonate 1. The reaction proceeded under catalyst-free and neat conditions and the corresponding phosphonates 2 were afforded in good yields.
Sulphenylation of Phosphonates. A Facile Synthesis of α-Phosphoryl Sulphides and S,S-Acetals of Oxomethanephosphonates
Mikolajczyk, Marian,Balczewski, Piotr,Grzejszczak, Slawomir
, p. 127 - 129 (2007/10/02)
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