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(1S,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 2-ethyl ester 1-methyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 67463-06-3 Structure
  • Basic information

    1. Product Name: (1S,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 2-ethyl ester 1-methyl ester
    2. Synonyms:
    3. CAS NO:67463-06-3
    4. Molecular Formula:
    5. Molecular Weight: 248.279
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 67463-06-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1S,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 2-ethyl ester 1-methyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1S,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 2-ethyl ester 1-methyl ester(67463-06-3)
    11. EPA Substance Registry System: (1S,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 2-ethyl ester 1-methyl ester(67463-06-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 67463-06-3(Hazardous Substances Data)

67463-06-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 67463-06-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,4,6 and 3 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 67463-06:
(7*6)+(6*7)+(5*4)+(4*6)+(3*3)+(2*0)+(1*6)=143
143 % 10 = 3
So 67463-06-3 is a valid CAS Registry Number.

67463-06-3Downstream Products

67463-06-3Relevant articles and documents

Rhodium-catalyzed enantioselective cyclopropanation of electron-deficient alkenes

Wang, Hengbin,Guptill, David M.,Varela-Alvarez, Adrian,Musaev, Djamaladdin G.,Davies, Huw M. L.

, p. 2844 - 2850 (2013)

The rhodium-catalyzed reaction of electron-deficient alkenes with substituted aryldiazoacetates and vinyldiazoacetates results in highly stereoselective cyclopropanations. With adamantylglycine derived catalyst Rh2(S-TCPTAD)4, high asymmetric induction (up to 98% ee) can be obtained with a range of substrates. Computational studies suggest that the reaction is facilitated by weak interaction between the carbenoid and the substrate carbonyl but subsequently proceeds via different pathways depending on the nature of the carbonyl. Acrylates and acrylamides result in the formation of cyclopropanation products while the use of unsaturated aldehydes and ketones results in the formation of epoxides.

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