67471-55-0Relevant academic research and scientific papers
Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes. Preparation of 2-fluoroallylic ethers, esters and alcohols
Novikov, Maxim A.,Volchkov, Nikolai V.,Lipkind, Maria B.,Nefedov, Oleg M.
supporting information, p. 131 - 143 (2015/10/05)
Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes in MeOH, NaOAc/AcOH, NaOAc/DMF, HCO2Na/HCO2H or water/dioxane affords 2-fluoroallylic ethers, esters or alcohols in moderate to excellent yields. Th
SOLVOLYSIS OF gem-DIHALOGENOCYCLOPROPANES IN THE PRESENCE OF SILVER SALTS
Molchanov, A. P.,Kostikov, R. R.
, p. 429 - 435 (2007/10/02)
The methanolysis and acetolysis of substituted gem-dibromo- and gem-bromofluorocyclopropanes in the presence of silver salts lead to the products from opening of the three-membered ring.Their ratio is determined by the charge distribution in the intermediate cation.When heated the obtained thermodynamically less stable isomers isomerize to the more stable isomers.
