674799-05-4Relevant articles and documents
Stereoselective migration of sterically hindered organoboranes in cyclic and acyclic systems. A stereoselective allylic C-H activation reaction
Hupe, Eike,Denisenko, Dmitri,Knochel, Paul
, p. 9187 - 9198 (2007/10/03)
The thermal migration of cyclic and acyclic organoboranes were studied. In most cases, a stereoselective 1,2-dyotropic migration was observed, allowing the stereocontrol of three contiguous chiral centers. Scope and limitations of this thermal migration are presented.