675124-49-9Relevant articles and documents
A parallel synthesis approach towards a family of C-nucleosides
Adamo, Mauro F.A.,Adlington, Robert M.,Baldwin, Jack E.,Day, Anna L.
, p. 841 - 849 (2004)
A synthetic route was devised for a sugar based α-chloroketone, which was subsequently used to generate a family of C-nucleosides via parallel synthetic methodology.
Synthesis of C-Nucleosides via Radical Coupling Reaction
Togo, Hideo,Ishigami, Sachiko,Fujii, Misa,Ikuma, Toshihiro,Yokoyama, Masataka
, p. 2931 - 2942 (2007/10/02)
Photolysis of O-acyl derivatives of N-hydroxy-2-thiopyridone, prepared from tetrahydrofuran-2-carboxylic acid, D-ribofuranosylmethanoic acid, and D-ribopyranosylmethanoic acid, gave the corresponding C-nucleoside derivatives in the presence of heteroaromatic compounds via radical pathways.The essential step in this method is a radical coupling reaction of D-ribofuranosyl radical or D-ribopyranosyl radical and some heteroaromatic bases.This is a new method for the preparation of C-nucleosides using sugar carboxylic acids.