67519-73-7

Basic information

• Product Name: Acetamide, N-[(chlorodimethylsilyl)methyl]-N-methyl-
• CAS NO: 67519-73-7
• Molecular Formula: C6H14ClNOSi
• Molecular Weight: 179.722
• Mol File: 67519-73-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetamide, N-[(chlorodimethylsilyl)methyl]-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-[(chlorodimethylsilyl)methyl]-N-methyl-(67519-73-7)
• EPA Substance Registry System: Acetamide, N-[(chlorodimethylsilyl)methyl]-N-methyl-(67519-73-7)

Safety Data

• Hazardous Substances Data: 67519-73-7(Hazardous Substances Data)

Upstream product

• 1719-57-9 Chloro(chloromethyl)dimethylsilane 
• 7449-74-3 N-methyl-N-trimethylsilylacetamide 

Relevant articles and documents

Scheme of hydrolysis of five-coordinate chlorosilanes by X-ray diffraction data

Hydrolysis of monochelate five-coordinate chlorosilanes MeC(O)N(Me)CH 2SiMe2Cl (Ia), L7CH2SiMe 2Cl (Ib), L8CH2SiMe2Cl (Ic), PhtImCH2SiMe2Cl (Id), MeC(O)N(Me)CH2SiMePhCl (IIa), and Im5CH2SiMePhCl (IIe), containing a monoanionic C,O-chelating ligand LCH2 [L is an amide, n-membered lactam (L n), imide (Imn), or phthalimide (PhtIm) residue]. The structures of the starting chlorides and their hydrolysis products were established by means of X-ray diffraction analysis. Based on experimental and published data, a general scheme of hydrolysis of mono-C,O-chelate chlorosilanes was suggested, including initial formation of silyloxonium chlorides III and subsequent formation of disiloxane dihydrochlorides IV. Pleiades Publishing, Ltd., 2011.