1719-57-9Relevant articles and documents
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McBride, J. J.,Beachell, H. C.
, p. 2532 - 2533 (1948)
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N-(DIMETHYLCHLOROSILYLMETHYL)LACTAMS AND RELATED COMPOUNDS IN THE SYNTHESIS OF DISILOXANES. MOLECULAR AND CRYSTAL STRUCTURE OF 2,2,5-TRIMETHYL-3-(DIMETHYLCHLOROSILYLMETHYL)OXAZOLIDIN-4-ONE, 2,2-DIMETHYL-3-(DIMETHYLCHLOROSILYLMETHYL)-2H-1,3-BENZOXAZIN-4-ONE, AND 1-(DIMETHYLCHLOROSILYLME..
Artamkina, O. B.,Kramarova, E. P.,Shipov, A. G.,Baukov, Yu. I.,Macharashvili, A. A.,et al.
, p. 237 - 245 (2007/10/02)
By hydrolysis of N-(dimethylchlorosilylmethyl)lactams and some related oxygen-containing heteroanalogs in the presence of sodium hydrocarbonate or triethylamine and also by exchange reaction of 1-(dimethylchlorosilylmethyl)-2-pyrrolidone with hexamethyl- or bis(dimethylchloromethyl)disiloxane the corresponding disiloxanes were obtained.These compounds, according to IR data, lack intramolecular silicon-oxygen interaction.The x-ray structural data show that with decreasing size of the ring the length of the covalent O-Si bond increases from 1.988(2) Angstroem in 2,2-dimethyl-3-(dimethylchlorosilylmethyl)-2H-1,3-benzoxazin-4-one to 2.050(2) Angstroem in 1-(dimethylchlorosilylmethyl)-4-phenyl-2-pyrrolidone and still more sharply on introduction of an ether oxygen atom into the γ-lactam ring in 2,2,5-trimethyl-3-(dimethyl-chlorosilylmethyl)oxazolidin-4-one.
REACTIONS OF PERALKYLATED POLYSILANES WITH BENZOYL PEROXIDE
Chesnokova, T. A.,Kornev, A. N.,Semenov, V. V.,Kurskii, Yu. A.,Razuvaev, G. A.
, p. 934 - 937 (2007/10/02)
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