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(1R,4aR,8aS)-5,5,8a-Trimethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalene-1,2-dicarbaldehyde is a complex organic compound with a molecular formula of C13H18O2. It is a bicyclic molecule with a naphthalene core, featuring two aldehyde functional groups at the 1 and 2 positions. The structure is characterized by three methyl groups at the 5, 5, and 8a positions, and the stereochemistry is defined by the R, R, and S configurations at the 1, 4a, and 8a positions, respectively. (1R,4aR,8aS)-5,5,8a-Trimethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalene-1,2-dicarbaldehyde is likely to be found in the field of organic chemistry, potentially as an intermediate in the synthesis of more complex molecules or as a component in various chemical processes. Its specific applications and properties would depend on the context in which it is used, such as in pharmaceuticals, fragrances, or other industrial applications.

6752-77-8

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6752-77-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6752-77-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,7,5 and 2 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 6752-77:
(6*6)+(5*7)+(4*5)+(3*2)+(2*7)+(1*7)=118
118 % 10 = 8
So 6752-77-8 is a valid CAS Registry Number.

6752-77-8Relevant academic research and scientific papers

SYNTHESIS OF BOTH THE ENANTIOMERS OF POLYGODIAL, AN INSECT ANTIFEEDANT SESQUITERPENE

Mori, Kenji,Watanabe, Hidenori

, p. 273 - 282 (2007/10/02)

Both the natural and unnatural enantiomers of polygodial, an insect antifeedant sesquiterpene of the drimane family, were synthesized starting from (S)-3-hydroxy-2,2-dimethylcyclohexanone as a single chiral source.

Synthesis of all possible stereoisomers of polygodial

Guillerm, D.,Delarue, M.,Jalali-Naini, M.,Lemaitre, P.,Lallemand, J.-Y.

, p. 1043 - 1046 (2007/10/02)

The three possible isomers of polygodial, epimers at C-9, cis and trans fused, are described.Controlled kinetic and thermodynamic epimerizations allow preparation of all stereoisomers from the same key intermediate.

EFFICIENT TOTAL SYNTHESES OF POLYGODIAL AND DRIMENIN.

Jallali-Naini, M.,Boussac, G.,Lemaitre, P.,Larcheveque, M.,Guillerm, D.,Lallemand, J-Y

, p. 2995 - 2998 (2007/10/02)

A short and stereoselective total synthesis of (+/-) polygodial and drimenin is presented.The efficiency of the synthesis is due to the easy access to intermediate diol 4 and its successful direct oxidation into polygodial.

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