675855-29-5Relevant academic research and scientific papers
Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents
Lee, Yunmi,Akiyama, Katsuhiro,Gillingham, Dennis G.,Brown, M. Kevin,Hoveyda, Amir H.
, p. 446 - 447 (2008/09/20)
An efficient method for catalytic asymmetric allylic alkylation (AAA) of allylic phosphates with vinylaluminum reagents is reported. The vinylmetal reagents are prepared by reaction of commercially available DIBAL-H and a terminal alkyne. The resulting vi
Stereoselective Construction of Acyclic Carbon Chains by a One-Pot Coupling Process Based on Alkenyloxazoline-Titanium Complexes
Mitsui, Kazuhisa,Sato, Takayuki,Urabe, Hirokazu,Sato, Fumie
, p. 490 - 492 (2007/10/03)
A versatile organometallic intermediate, an alkenyloxazoline-titanium complex, has been developed that enables one-pot multicomponent diastereoselective and asymmetric coupling processes to be achieved in a remarkably efficient manner (see scheme).
