676153-95-0Relevant academic research and scientific papers
Base induced chiral substituted furans and imidazoles from carbohydrate-derived 2-haloenones
Mal, Kanchan,Das, Indrajit
, p. 932 - 945 (2016)
Chiral substituted furans and imidazoles are key intermediates to access biologically important molecules. We describe herein a catalyst/ligand free cascade Michael-type addition/intramolecular cyclization/carbohydrate-ring opening of 2-haloenones with 1,
Gold(III) chloride catalyzed synthesis of chiral substituted 3-formyl furans from carbohydrates: Application in the synthesis of 1,5-dicarbonyl derivatives and furo[3,2-c]pyridine
Mal, Kanchan,Sharma, Abhinandan,Das, Indrajit
supporting information, p. 11932 - 11945 (2014/10/15)
This report describes a gold(III)-catalyzed efficient general route to densely substituted chiral 3-formyl furans under extremely mild conditions from suitably protected 5-(1-alkynyl)-2,3-dihydropyran-4-one using H2O as a nucleophile. The react
Stereoselective michael-type addition of organocopper reagents to enones derived from glycals in the synthesis of 2-phosphono-α-C-glycosides
Leonelli, Francesca,Capuzzi, Marinella,Calcagno, Vincenzo,Passacantilli, Pietro,Piancatelli, Giovanni
, p. 2671 - 2676 (2007/10/03)
Michael-type additions of various organocopper reagents to the novel carbohydrate-derived 2-(diethoxyphosphoryl)hex-1-en-3-uloses are described. The reactions have proved to be rapid, clean and stereoselective, giving rise to the formation of 3-oxo-2-phos
Synthesis of model ring systems related to C10-C18 analogues of the mycalamides/theopederins
Gardiner, John M.,Mills, Richard,Fessard, Thomas
, p. 1215 - 1217 (2007/10/03)
Conjugate addition to D-galactose-derived pyranones 8 and 10, with in situ enolate alkylation, or protonation, provides pyranones 11-13 or 16-19. These are related to the C10-C18 fragment of the mycalamides and provide a short entry to C10, C11, C14 and C
