67616-99-3Relevant articles and documents
Pressure-dependent Isotope Effect in the Reaction of Silylene (SiH2, 1A1) with Acetylene and Acetylene
Becerra, Rosa,Frey, H. Monty,Mason, Ben P.,Walsh, Robin
, p. 1050 - 1052 (1993)
Direct, time resolved measurements of absolute rate constants for reaction of SiH2(1A1) with C2H2 and C2D2 have revealed a pressure (and temperature) dependent isotope effect characteristic of an association process yielding an intermediate (silirene) which undergoes, amongst other reactions, a degenerate isotopic scrambling process.
Silacyclopropen: Bildung durch Hochvakuum-Blitzpyrolyse und matrixspektroskopische Identifizierung
Maier, Guenther,Pacl, Harald,Reisenauer, Hans Peter
, p. 1627 - 1629 (2007/10/02)
Stichworte: Blitzpyrolyse.Gespannte Ringe.Photochemie.Siliciumverbindungen