Journal of the Chemical Society. Chemical communications p. 1050 - 1052 (1993)
Update date:2022-08-04
Topics:
Becerra, Rosa
Frey, H. Monty
Mason, Ben P.
Walsh, Robin
Direct, time resolved measurements of absolute rate constants for reaction of SiH2(1A1) with C2H2 and C2D2 have revealed a pressure (and temperature) dependent isotope effect characteristic of an association process yielding an intermediate (silirene) which undergoes, amongst other reactions, a degenerate isotopic scrambling process.
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