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676226-33-8

(meso-tetratolylporphyrinato)Ru(o-tolNO)2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 676226-33-8 Structure

  • Basic information

    1. Product Name: (meso-tetratolylporphyrinato)Ru(o-tolNO)2
    2. Synonyms:
    3. CAS NO:676226-33-8
    4. Molecular Formula:
    5. Molecular Weight: 1012.19
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 676226-33-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (meso-tetratolylporphyrinato)Ru(o-tolNO)2(CAS DataBase Reference)
    10. NIST Chemistry Reference: (meso-tetratolylporphyrinato)Ru(o-tolNO)2(676226-33-8)
    11. EPA Substance Registry System: (meso-tetratolylporphyrinato)Ru(o-tolNO)2(676226-33-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 676226-33-8(Hazardous Substances Data)

676226-33-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 676226-33-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,7,6,2,2 and 6 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 676226-33:
(8*6)+(7*7)+(6*6)+(5*2)+(4*2)+(3*6)+(2*3)+(1*3)=178
178 % 10 = 8
So 676226-33-8 is a valid CAS Registry Number.

676226-33-8Relevant articles and documents

Synthesis and molecular structures of nitrosoarene metalloporphyrin complexes of ruthenium

Lee, Jonghyuk,Twamley, Brendan,Richter-Addo, George B.

, p. 189 - 196 (2004)

Several new ruthenium porphyrins containing nitrosoarene ligands have been synthesized and characterized by IR and 1H NMR spectroscopy, and by single-crystal X-ray crystallography. Bis-nitrosoarene complexes of the form (por)Ru(ArNO)2 (Ar = aryl group; por = TPP, TTP; TPP = tetraphenylporphyrinato dianion, TTP = tetratolylporphyrinato dianion) were prepared in good yields from the reaction of the nitrosoarenes with (por)Ru(CO). The IR spectra of the complexes (as KBr pellets) display new bands in the 1346-1350 cm-1 region due to vNO. Reactions of the (por)Ru(ArNO)2 complexes with excess pyridine and 1-methylimidazole produce the mono-nitrosoarene complexes (por)Ru(ArNO)(py) and (por)Ru(ArNO)(1-MeIm), respectively. The IR spectra of these mono-nitrosoarene complexes reveal a lowering of vNO by 14-44 cm-1, a feature consistent with the replacement of one of the π-acid ArNO ligands with the more basic pyridine and 1-MeIm ligands. The solid-state molecular structures of two members of each of the three classes of compounds, namely (por)Ru(ArNO)2, (por)Ru(ArNO)(py) and (por)Ru(ArNO)(1-MeIm) were determined by single-crystal X-ray diffraction, and reveal the N-binding mode of the ArNO ligands.

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