(meso-tetratolylporphyrinato)Ru(o-tolNO)2

Base Information

• Chemical Name: (meso-tetratolylporphyrinato)Ru(o-tolNO)2
• CAS No.: 676226-33-8
• Molecular Formula: C₆₂H₅₀N₆O₂Ru
• Molecular Weight: 1012.19
• Mol file: 676226-33-8.mol

Synonyms:

Chemical Property of (meso-tetratolylporphyrinato)Ru(o-tolNO)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (meso-tetratolylporphyrinato)Ru(o-tolNO)2

There total 1 articles about (meso-tetratolylporphyrinato)Ru(o-tolNO)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

carbonyl(meso-tetrakis(4-tolyl)porphyrinato)ruthenium(II) (75888-64-1) + 2-nitrosotoluene (611-23-4) → (meso-tetratolylporphyrinato)Ru(o-tolNO)2 (676226-33-8)

Guidance literature:

In dichloromethane; under N2 atm. soln. (TTP)Ru(CO) and o-tolNO in CH2Cl2 was stirred at room temp. for 30 min; solvent was removed in vacuo, residue was dissolved in CH2Cl2 and filtered through neutral alumina in air, slow evapn. CH2Cl2 soln. in air;

DOI:10.1039/b315051h

Reference yield: 58.0%

1-methyl-1H-imidazole (616-47-7) + (meso-tetratolylporphyrinato)Ru(o-tolNO)2 (676226-33-8) → (meso-tetratolylporphyrinato)Ru(o-tolNO)(1-methylimidazole) (676226-41-8)

Guidance literature:

In dichloromethane; under N2 atm. to soln. (TTP)Ru(o-tolNO)2 in CH2Cl2 1-MeIm was added and stirred at room temp. for 30 min; solvent was removed in vacuo, recrystn. from CH2Cl2-hexane (1:3) at -20°C;

DOI:10.1039/b315051h

Reference yield:

dichloromethane (75-09-2) + (meso-tetratolylporphyrinato)Ru(o-tolNO)2 (676226-33-8) → (meso-tetratolylporphyrinato)Ru(o-tolNO)2*CH2Cl2 (676226-45-2)

Guidance literature:

In hexane; dichloromethane;

DOI:10.1039/b315051h

upstream raw materials:

carbonyl(meso-tetrakis(4-tolyl)porphyrinato)ruthenium(II)

2-nitrosotoluene

Downstream raw materials:

(meso-tetratolylporphyrinato)Ru(o-tolNO)2*CH₂Cl₂

(meso-tetratolylporphyrinato)Ru(o-tolNO)(1-methylimidazole)