676264-87-2

Upstream product

• 74-85-1 ethene 
• 676151-70-5 [RhCl(H)2((CH₃)2C₆H₃CH₂CH₂P(C(CH₃)3)2)2] 
• 676151-70-5 [RhH2Cl(2,6-Me2C6H3CH2CH2PtBu2-κP)2] 
• 461052-81-3 2,6-Me₂C₆H₃CH₂CH₂PtBu₂ 

Downstream Products

• 461052-90-4 [RhCl₂(H)(C₂H₄)((CH₃)2C₆H₃CH₂CH₂P(C(CH₃)3)2)] 
• 461052-84-6 [Rh(μ-Cl)Cl(C2H5)(2,6-Me2C6H3CH2CH2PtBu2-κP)]2 
• 461052-83-5 [RhH2(μ-Cl)(2,6-Me2C6H3CH2CH2PtBu2-κP)]2 
• 676151-70-5 [RhH2Cl(2,6-Me2C6H3CH2CH2PtBu2-κP)2] 

Relevant academic research and scientific papers

Mono- and dinuclear rhodium(I) and rhodium(III) complexes with the bulky phosphine 2,6-Me2C6H3CH2 CH2PtBu2, including the first structurally characterized cis-configurated dicarbonyl compou

The bulky functionalized phosphine 2,6-Me2C6H3CH2CH2 PtBu2 (3) was prepared in a stepwise fashion from the Grignard reagent 2,6-Me2C6H3CH2 CHsub

An unprecedented dinuclear alkylrhodium(III) complex built up by two 14-electron [RhCl2(alkyl)(PR3)] units

Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type. Copyright