67642-35-7Relevant academic research and scientific papers
SYNTHESIS OF PHEROMONES, IV. CHEMISTRY OF THE WITTIG REACTION, I. EFFECTS OF REACTION CONDITIONS ON THE STEREOSELECTIVITY AND YIELD OF THE WITTIG REACTION
Vinczer, Peter,Juvancz, Zoltan,Novak, Lajos,Szantay, Csaba
, p. 797 - 820 (2007/10/02)
The reactions of nonstabilized triphenylphosphorus ylides with aldehydes have been studied in detail.The stereochemistry and yields of the alkene products are highly dependent upon base used for the generation of the ylide, the solvent and reaction temperature.The synthesis of sex pheromone components by Wittig reaction are also described.
Synthese von zweifach ueberbrueckten 2,5-Diamino-1,4-dialkyl-3,6-dimethoxybenzol-Derivaten als -Praerotaxane
Schill, Gottfried,Ortlieb, Heribert
, p. 877 - 890 (2007/10/02)
Starting with 2,5-dimethoxyterephthaldialdehyde (1) and the triphenylphosphorane 2 the double bridged 2,5-diaminohydroquinone derivative 20 is synthesised in a multistep reaction sequence.Via the dibromide 21 as intermediate, the -prerotaxane 22 is obt
