676557-82-7Relevant academic research and scientific papers
Versatility and dynamics of the copper(I) coordination sphere in sterically hindering tris(pyrazolyl)methane-incorporating macrobicycles
Wang, Leyong,Chambron, Jean-Claude,Espinosa, Enrique
, p. 327 - 336 (2009)
Two arene-capped macrobicycles (1 and 2) incorporating the tris(pyrazolyl)methane (Tpm) chelate have been prepared from a benzylthiol-functionalized Tpm precursor (3). Reaction of either macrobicycle with Cu(CH3CN)4+ leads
Synthesis of a macrobicycle incorporating the tris(pyrazolyl)methane ligand
Wang, Leyong,Chambron, Jean-Claude
, p. 747 - 750 (2007/10/03)
Steric crowding of the 3-position of tris(pyrazolyl)borate and -methane ligands has produced tetrahedral metal complexes with controlled reactivity. As an alternative, we propose to incorporate the tris(pyrazolyl)methane chelate in a macrobicyclic structu
