676557-86-1

Upstream product

• 28791-97-1 tris(3,5-dimethylpyrazolyl)methane 
• 676557-81-6 ethanethioic acid S-[[3-(1H-pyrazol-3-yl)phenyl]methyl] ester 
• 676557-84-9 S,S',S-[methylidynetris(1H-pyrazole-1,3-diyl-3,1-phenylene-methylene)] triethanethioate 
• 197093-23-5 3-(1H-pyrazol-3-yl)benzenemethanol 
• 676557-82-7 3-(1H-pyrazol-3-yl)benzenemethanethiol 

Relevant academic research and scientific papers

Synthesis and functional group transformations of tris(pyrazol-1-yl)methane (Tpm) and -ethane (Tpe) derivatives for the preparation of sterically hindered chelating macrobicycles

Tris(pyrazol-1-yl)methane (Tpm) and -ethane (Tpe) chelate derivatives bearing meta-benzonitrile groups in the position ortho to the coordinating nitrogen atom have been prepared from 3-(1H-pyrazol-3-yl)benzonitrile, and subjected to functional group trans

Versatility and dynamics of the copper(I) coordination sphere in sterically hindering tris(pyrazolyl)methane-incorporating macrobicycles

Two arene-capped macrobicycles (1 and 2) incorporating the tris(pyrazolyl)methane (Tpm) chelate have been prepared from a benzylthiol-functionalized Tpm precursor (3). Reaction of either macrobicycle with Cu(CH3CN)4+ leads

Synthesis of a macrobicycle incorporating the tris(pyrazolyl)methane ligand

Steric crowding of the 3-position of tris(pyrazolyl)borate and -methane ligands has produced tetrahedral metal complexes with controlled reactivity. As an alternative, we propose to incorporate the tris(pyrazolyl)methane chelate in a macrobicyclic structu