67698-66-2

Basic information

• Product Name: Benzaldehyde, 2-(2-methylphenoxy)-
• CAS NO: 67698-66-2
• Molecular Formula: C14H12O2
• Molecular Weight: 212.248
• Mol File: 67698-66-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-(2-methylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-(2-methylphenoxy)-(67698-66-2)
• EPA Substance Registry System: Benzaldehyde, 2-(2-methylphenoxy)-(67698-66-2)

Safety Data

• Hazardous Substances Data: 67698-66-2(Hazardous Substances Data)

Upstream product

• 95-48-7 ortho-cresol 
• 446-52-6 2-Fluorobenzaldehyde 
• 552-89-6 2-nitro-benzaldehyde 
• 16419-60-6 2-Methylphenylboronic acid 
• 6630-33-7 ortho-bromobenzaldehyde 
• 89-98-5 2-chloro-benzaldehyde 
• 26260-02-6 2-iodobenzaldehyde 

Downstream Products

• 1400883-61-5 C₂₀H₁₈O₄S 
• 26321-31-3 2-(p-tolyloxy)phenol 
• 7320-53-8 4-methyl-dibenzofuran 
• 617-01-6 o-tolyl 2-hydroxybenzoate 
• 5396-28-1 4-methylxanthen-9-one 

Relevant articles and documents

An organocatalytic method for the synthesis of some novel xanthene derivatives by the intramolecular Friedel-Crafts reaction

An efficient organocatalytic method for the synthesis of new substituted 9-arylxanthenes (2a-2u) starting from diarylcarbinol compounds with an arenoxy group (1a-1u) has been developed using the intramolecular Friedel-Crafts reaction. The substrates were

Palladium-catalyzed intramolecular C-H arylation of arenes using tosylates and mesylates as electrophiles

This paper describes a method for the palladium catalyzed intramolecular C-H arylation using tosylates and mesylates as electrophiles. The transformation is efficient for the synthesis of various heterocyclic motifs including furans, carbazoles, indoles, and lactams. Additionally, a protocol for the one-pot sequential tosylation/arylation of phenol derivatives is presented.

The coupling of arylboronic acids with nitroarenes catalyzed by rhodium

The coupling of arylboronic acids with electron-deficient nitroarenes was realized for the first time by using a rhodium(I) catalyst under an air atmosphere, achieving unsymmetrical diaryl ethers with yields ranging from poor to good. From a deuterium labeling experiment, the oxygen atom is derived from ambient water. The efficiency of this reaction was demonstrated by its compatibility with fluoro, bromo, chloro, and trifluoromethyl groups.