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CAS

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677032-06-3

(4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 677032-06-3 Structure

  • Basic information

    1. Product Name: (4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one
    2. Synonyms: (4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one
    3. CAS NO:677032-06-3
    4. Molecular Formula:
    5. Molecular Weight: 305.374
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 677032-06-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one(CAS DataBase Reference)
    10. NIST Chemistry Reference: (4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one(677032-06-3)
    11. EPA Substance Registry System: (4R,3'S,4'S)-4-isopropyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one(677032-06-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 677032-06-3(Hazardous Substances Data)

677032-06-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 677032-06-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,7,7,0,3 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 677032-06:
(8*6)+(7*7)+(6*7)+(5*0)+(4*3)+(3*2)+(2*0)+(1*6)=163
163 % 10 = 3
So 677032-06-3 is a valid CAS Registry Number.

677032-06-3Relevant articles and documents

Enecarbamates as Selective Substrates in Oxidations: Chiral-Auxiliary-Controlled Mode Selectivity and Diastereoselectivity in the [2+2] Cycloaddition and Ene Reaction of Singlet Oxygen and in the Epoxidation by DMD and mCPBA

Adam, Waldemar,Bosio, Sara G.,Turro, Nicholas J.,Wolff, Barbara T.

, p. 1704 - 1715 (2007/10/03)

The stereochemical course of the oxidation of chiral oxazolidinone-substituted enecarbamates has been studied for singlet oxygen (1O2), dimethyldioxirane (DMD), and m-chloroperbenzoic acid (mCPBA) by examining of the special structural and stereoelectronic features of the enecarbamates. Valuable mechanistic insight into these selective oxidations is gained. Whereas the R1 substituent on the chiral auxiliary is responsible for the steric shielding of the double bond and determines the sense of the π-facial diastereoselectivity, structural characteristic such as the Z/E configuration and the nature of the R 2 group on the double bond are responsible for the extent of the diastereoselectivity. Stereoelectronic steering by the vinylic nitrogen functionality controls the mode selectivity (ene reaction vs [2+2] cycloaddition) in the case of 1O2.

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