677353-08-1Relevant academic research and scientific papers
Diastereocontrol in open-chain nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group
Betson, Mark S.,Fleming, Ian,Ouzman, Jacqueline V.A.
, p. 4017 - 4024 (2007/10/03)
The bis[dimethyl(phenyl)silyl]cuprate reagent introduces a silyl group to the β-position of three α,β-unsaturated esters: methyl Z-4-dimethyl(phenyl)silylpent-2-enoate 11, and methyl Z- and E-(1′-dimethylphenylsilylbenzyl)but-2-enoates 14 and 15, diastere
