677745-84-5

Upstream product

• 677745-95-8 C₃₉H₄₈O₂Si₂ 
• 4720-83-6 6-oxabicyclo[3.2.1]oct-3-en-7-one 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 127308-75-2 (1R,5R)-5-(hydroxymethyl)-2-cyclohexen-1-ol 
• 54911-89-6 cis-methyl 5-hydroxycyclohex-3-enecarboxylate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 19914-92-2 (+/-)-4-iodo-6-oxabicyclo[3.2.1]octan-7-one 
• 1166841-75-3 (R)-5-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohex-2-enone 
• 1375467-36-9 (R)-3-(tert-butyldiphenylsilanyloxymethyl)-hex-5-enal 
• 1375467-38-1 (R)-5-(tert-butyldiphenylsilanyloxymethyl)-octa-1,7-dien-3-one 
• 1375467-34-7 (S)-methanesulfonic acid 2-(tert-butyldiphenylsilanyloxymethyl)-pent-4-enyl ester 
• 1375467-35-8 (R)-3-(tert-butyldiphenylsilanyloxymethyl)-hex-5-enenitrile 

Downstream Products

• 677745-96-9 Benzoic acid (1S,2R,4R,6S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-7-oxa-bicyclo[4.1.0]hept-2-yl ester 
• 1168139-99-8 (1R,2S,3R,5S)-5-(hydroxymethyl)cyclohexane-1,2,3-triol 
• 1375467-39-2 (1R,2S,3R,5S)-5-(tert-butyldiphenylsilyloxymethyl)cyclohexane-1,2,3-triol 
• 677745-98-1 Benzoic acid (1R,2R,3S,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-3,4-bis-methoxymethoxy-cyclohexyl ester 
• 677745-88-9 Benzoic acid (1R,2S,3S,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-3,4-bis-methoxymethoxy-cyclohexyl ester 
• 677746-00-8 Benzoic acid (1S,2R,3S,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-3,4-bis-methoxymethoxy-cyclohexyl ester 
• 677745-92-5 Benzoic acid (1S,2S,3S,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-3,4-bis-methoxymethoxy-cyclohexyl ester 
• 677745-99-2 Benzoic acid (1R,2R,3R,5R,6R)-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-5,6-bis-methoxymethoxy-cyclohexyl ester 
• 677745-90-3 Benzoic acid (1R,2S,3R,5R,6R)-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-hydroxy-5,6-bis-methoxymethoxy-cyclohexyl ester 
• 677745-87-8 Benzoic acid (1R,3R,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3,4-bis-methoxymethoxy-2-oxo-cyclohexyl ester 
• 677745-91-4 Benzoic acid (1S,3R,4R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3,4-bis-methoxymethoxy-2-oxo-cyclohexyl ester 
• 677745-89-0 Benzoic acid (1S,3R,5R,6R)-3-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-bis-methoxymethoxy-2-oxo-cyclohexyl ester 
• 677745-86-7 (1R,2R,3S,4R,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,4-bis-methoxymethoxy-cyclohexane-1,2-diol 
• 677745-97-0 ((1S,4S,5R)-4,5-Bis-methoxymethoxy-cyclohex-2-enylmethoxy)-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

Stereoselective synthesis of a novel natural carbasugar and analogues from hydroxymethylated cycloalkenone scaffolds

Novel carbasugars from Streptomyces lincolnensis have been synthesized from an enantiomerically pure 5-hydroxymethyl-cyclohex-2-enone scaffold via a stereoselective approach. Several structural analogues of those carbasugars have also been synthesized in a stereoselective manner from hydroxymethylated cycloalkenone derivatives.

Practical syntheses of enantiopure carbasugars: Carba-β-altrose, carba-β-mannose, carba-β-idose, and carba-β-talose derivatives

D and L forms of carba-β-altrose 8, carba-β-mannose 10a, carba-β-idose 12, carba-β-talose 14 derivatives were prepared from (±)-3-cyclohexene-1-carboxylic acid 1. Homochiral diol compounds D-5a and L-5a, which were prepared from 1 via enzyme resolution of