67776-12-9

Upstream product

• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 193287-42-2 methyl 2,3-di-O-benzyl-6-chloro-6-deoxy-4-O-methyl-α-D-glucopyranoside 
• 51433-17-1 Methyl 2,3-di-O-benzyl-4-O-methyl-α-D-glucopyranoside 
• 193287-44-4 methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-methyl-α-D-glucopyranoside 
• 193287-46-6 methyl 6-amino-2,3-di-O-benzyl-6-deoxy-4-O-methyl-α-D-glucopyranoside 
• 193287-50-2 methyl 2,3-di-O-benzyl-6-chloroacetamido-6-deoxy-4-O-methyl-α-D-glucopyranoside 
• 193287-53-5 methyl 2,3-di-O-benzyl-6-deoxy-4-O-methyl-6-succinimido-α-D-glucopyranoside 
• 193287-54-6 methyl 2,3-di-O-benzyl-6-deoxy-4-O-methyl-6-succinamido-α-D-glucopyranoside 
• 193287-48-8 methyl 2,3-di-O-benzyl-6-(N,N-bis-ethoxycarbonylmethylamino)-6-deoxy-4-O-methyl-α-D-glucopyranoside 
• 193287-60-4 N-(methyl 2,3-di-O-benzyl-6-deoxy-4-O-methyl-α-D-glucopyranoside-6-ylaminocarbonyl)-L-aspartic acid dimethylester 
• 193287-55-7 methyl 2,3-di-O-benzyl-6-deoxy-4-O-methyl-6-{4-[N,N-bis-(methoxycarbonylmethyl)-amino]-succinamido}-α-D-glucopyranoside 
• 193287-51-3 methyl 2,3-di-O-benzyl-6-{[N,N-bis-(benzyloxycarbonylmethyl)-amino]-acetamido}-6-deoxy-4-O-methyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of novel amino acid glycoside conjugates

A new class of non-anomeric amino acid glycoconjugates can be prepared starting from either ω-amino- or ω-halodeoxyglucosides. Treatment of an ether-protected methyl 7-amino-6,7-dideoxy-α-D-glucoheptopyranoside with methyl aspartate isocyanate gave an urea-linked conjugate of methyl glucoheptopyranoside and aspartic acid. Nucleophilic displacement of the ether-protected methyl 6-chloro-6-deoxy-α-D-glucopyranoside with potassium succinimide followed by imide ring opening and amidation of the succinic acid monoamide with dimethyl iminodiacetate led to a conjugate of methyl 6-amino-6-deoxy-α-D-glucopyranoside and iminoodiacetate bridged by succinate.

Halogenation of carbohydrates by triphenylphosphine complex reagents in highly concentrated solution under microwave activation or conventional heating

Halogenation of carbohydrates with triphenylphosphine and carbon tetrachloride, hexachloroethane or 1,2-dibromotetrachloroethane was shown to be very efficient in highly concentrated solutions of nonpolar solvents such as toluene or 1,2-dichloroethane, wi