678166-35-3

Upstream product

• 773-64-8 2-mesitylenesulphonyl chloride 
• 112245-13-3 (S)-tert-leucinol 
• 678166-23-9 (2S)-N-(2,4,6-trimethylbenzenesulfonyl)-2-amino-3,3-dimethyl-butanol 
• 148838-44-2 N-((S)-1-Formyl-2,2-dimethyl-propyl)-2,4,6-trimethyl-benzenesulfonamide 
• 678166-29-5 methyl (4R,2E)-2,5,5-trimethyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-enoate 

Downstream Products

• 221278-61-1 (4R,2E)-O-methoxycarbonyl-2,5,5-trimethyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-en-1-ol 

Relevant academic research and scientific papers

Stereodivergent synthesis of chiral 2-alkenylaziridines: Palladium(0)-catalyzed 2,3-cis-selective aziridination and base-mediated 2,3-trans-selective aziridination

Whereas treatment of the allylic mesylates of N-protected 2-alkyl-4-amino-(E)-2-alken-1-ols with sodium hydride in DMF yields exclusively the corresponding thermodynamically less stable 2,3-trans-2-alkenyl-3- alkylaziridines, exposure of the methyl carbon