67833-43-6

Basic information

• Product Name: Benzene, [(1-chloro-2-methylpropyl)sulfinyl]-
• CAS NO: 67833-43-6
• Molecular Formula: C10H13ClOS
• Molecular Weight: 216.732
• Mol File: 67833-43-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-chloro-2-methylpropyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-chloro-2-methylpropyl)sulfinyl]-(67833-43-6)
• EPA Substance Registry System: Benzene, [(1-chloro-2-methylpropyl)sulfinyl]-(67833-43-6)

Safety Data

• Hazardous Substances Data: 67833-43-6(Hazardous Substances Data)

Upstream product

• 72653-48-6 α-chloroisobutyl phenyl sulfide 
• 108-98-5 thiophenol 
• 13307-61-4 Isobutylthiobenzene 
• 22456-89-9 isobutyl phenyl sulfoxide 

Downstream Products

• 102104-34-7 1-(1-Benzenesulfinyl-1-chloro-2-methyl-propyl)-cyclohexanol 
• 95110-76-2 2''-isopropyl-2''-phenylsulfinyldispiro<1,3-dioxolane-2,1'-cyclohexane-4',1''-oxirane> 
• 95110-75-1 2'-isopropyl-2'-phenylsulfinylspiro 
• 96335-97-6 (1-Chloro-2-methyl-propenylsulfanyl)-benzene 

Relevant articles and documents

α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. I. A Novel Synthesis of Dialkyl Ketones and a Synthesis of Aldehydes from Ketones by One Carbon Elongation

Treatment of α,β-epoxy sulfoxides, prepared from 1-chloroalkyl phenyl sulfoxides with ketones or aldehydes, with sodium benzeneselenolate gives dialkyl ketones or aldehydes in good yields under mild conditions.The mechanism of this reaction and an application of this process to a formal total synthesis of dihydrojasmone are described.