67834-63-3Relevant academic research and scientific papers
OO-tert-BUTYL ALKOXY- AND ARYLOXYALKOXYALKYL MONOPEROXYCARBONATES AND THEIR REACTIVITY
Fomin, V. A.,Etlis, V. S.,Aleksandrova, Z. I.,Ivanova, N. N.
, p. 251 - 257 (2007/10/02)
A series of monopercarbonates were obtained from tert-butyl hydroperoxide and the chloroformates of diethylene (propylene) monoethers.The kinetics of their thermal dissociation at 110-140 deg C in organic solvents were investigated.The products from the homolysis of the peroxy esters were investigated, and it was established that the free radicals which form react preferentially with the hydrogen of the C-H bond in the organic fragment of the initial monoperoxy carbonate or its decomposition products.A scheme for the transformations of the obtained free-radicalparticles is proposed on the basis of the kinetic investigations and the balance of the thermolysis products.
